Direct Oxidative Conversion of Graphite Into Exfoliated Graphites. The Kinetic Model, Products, Mechanism

S. B. Lyubchik; V. A. Kucherenko; A. P. Yaroshenko

doi:10.1080/10587259408050090

Direct Oxidative Conversion of Graphite Into Exfoliated Graphites. The Kinetic Model, Products, Mechanism

S. B. Lyubchik, V. A. Kucherenko, A. P. Yaroshenko

NASU - Lytvynenko Institute of Physical Organic Chemistry and Coal Chemistry

Resultado de pesquisa › revisão de pares

4 Citações (Scopus)

Resumo

The process of thermally initiated synthesis of acceptor type graphite intercalation compounds (GICs) and the products of their thermolysis, i.e. exfoliated graphite (EG) has been considered within the scope of common kinetic model. Analysis of the data available in literature and results of present work indicate that in some cases direct oxidative conversion (DOC) of graphite into EG without specified GIC formation can be realized. DOC-process has been discovered for powder “graphite - M2+(N03)2-” mixtures at the temperature 300°C. The conditions for DOC-process realization are considered.

Idioma original	Inglês
Páginas (de-até)	107-113
Número de páginas	7
Revista	Molecular Crystals and Liquid Crystals
Volume	244
Número de emissão	1
DOIs	https://doi.org/10.1080/10587259408050090
Estado da publicação	Publicadas - abr. 1994
Publicado externamente	Sim

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abstract = "The process of thermally initiated synthesis of acceptor type graphite intercalation compounds (GICs) and the products of their thermolysis, i.e. exfoliated graphite (EG) has been considered within the scope of common kinetic model. Analysis of the data available in literature and results of present work indicate that in some cases direct oxidative conversion (DOC) of graphite into EG without specified GIC formation can be realized. DOC-process has been discovered for powder “graphite - M2+(N03)2-” mixtures at the temperature 300°C. The conditions for DOC-process realization are considered.",

author = "Lyubchik, {S. B.} and Kucherenko, {V. A.} and Yaroshenko, {A. P.}",

year = "1994",

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AU - Lyubchik, S. B.

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AU - Yaroshenko, A. P.

PY - 1994/4

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N2 - The process of thermally initiated synthesis of acceptor type graphite intercalation compounds (GICs) and the products of their thermolysis, i.e. exfoliated graphite (EG) has been considered within the scope of common kinetic model. Analysis of the data available in literature and results of present work indicate that in some cases direct oxidative conversion (DOC) of graphite into EG without specified GIC formation can be realized. DOC-process has been discovered for powder “graphite - M2+(N03)2-” mixtures at the temperature 300°C. The conditions for DOC-process realization are considered.

AB - The process of thermally initiated synthesis of acceptor type graphite intercalation compounds (GICs) and the products of their thermolysis, i.e. exfoliated graphite (EG) has been considered within the scope of common kinetic model. Analysis of the data available in literature and results of present work indicate that in some cases direct oxidative conversion (DOC) of graphite into EG without specified GIC formation can be realized. DOC-process has been discovered for powder “graphite - M2+(N03)2-” mixtures at the temperature 300°C. The conditions for DOC-process realization are considered.

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Direct Oxidative Conversion of Graphite Into Exfoliated Graphites. The Kinetic Model, Products, Mechanism

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