Enhanced thermal stability of dielectric and energy storage properties in 0.4BCZT-0.6BTSn lead-free ceramics elaborated by sol-gel method

S. Khardazi; H. Zaitouni; A. Neqali; S. Lyubchyk; D. Mezzane; M. Amjoud; E. Choukri; Z. Kutnjak

doi:10.1016/j.jpcs.2023.111302

Enhanced thermal stability of dielectric and energy storage properties in 0.4BCZT-0.6BTSn lead-free ceramics elaborated by sol-gel method

S. Khardazi, H. Zaitouni, A. Neqali, S. Lyubchyk, D. Mezzane, M. Amjoud, E. Choukri, Z. Kutnjak

RCM2+ - Centro de Investigação em Gestão de Ativos e Engenharia de Sistemas

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Polycrystalline lead-free Ba_0.85Ca_0.15Zr_0.10Ti_0.90O₃ (BCZT), BaTi_0.89Sn_0.11O₃ (BTSn) and 0.4Ba_0.85Ca_0.15Zr_0.10Ti_0.90O₃–0.6BaTi_0.89Sn_0.11O₃ (0.4BCZT–0.6BTSn) ferroelectric ceramics were prepared via sol-gel process and their structural, dielectric and energy storage properties were studied. Pure perovskite structure was confirmed by X-ray diffraction analysis. The evolution of energy storage performances with temperature was studied. A Significant recoverable energy-storage density of 137.86 mJ/cm³ and high energy-storage efficiency of 86.19% under a moderate electric field of 30 kV/cm were achieved in the composite 0.4BCZT–0.6BTSn ceramic at 353 K. Moreover, excellent temperature stability (70–130 °C) of the energy storage efficiency (less than 3%) was achieved.

Original language	English
Article number	111302
Journal	Journal of Physics and Chemistry of Solids
Volume	177
DOIs	https://doi.org/10.1016/j.jpcs.2023.111302
Publication status	Published - Jun 2023

Bibliographical note

Publisher Copyright:
© 2023 Elsevier Ltd

Funding

This research is financially supported by the European Union Horizon 2020 Research and Innovation actions MSCA-RISE-ENGIMA (No. 778072 ) and MSCA-RISE-MELON (No. 872631 )

Funders	Funder number
European Union Horizon 2020 Research and Innovation actions MSCA-RISE-ENGIMA	778072
MSCA-RISE-MELON	872631

Keywords

Energy storage
Ferroelectrics
Lead-free
Perovskites
Sol-gel

Access to Document

10.1016/j.jpcs.2023.111302

Cite this

@article{6cb71c37b52a47ed957853ea43e0dc38,

title = "Enhanced thermal stability of dielectric and energy storage properties in 0.4BCZT-0.6BTSn lead-free ceramics elaborated by sol-gel method",

abstract = "Polycrystalline lead-free Ba0.85Ca0.15Zr0.10Ti0.90O3 (BCZT), BaTi0.89Sn0.11O3 (BTSn) and 0.4Ba0.85Ca0.15Zr0.10Ti0.90O3–0.6BaTi0.89Sn0.11O3 (0.4BCZT–0.6BTSn) ferroelectric ceramics were prepared via sol-gel process and their structural, dielectric and energy storage properties were studied. Pure perovskite structure was confirmed by X-ray diffraction analysis. The evolution of energy storage performances with temperature was studied. A Significant recoverable energy-storage density of 137.86 mJ/cm3 and high energy-storage efficiency of 86.19% under a moderate electric field of 30 kV/cm were achieved in the composite 0.4BCZT–0.6BTSn ceramic at 353 K. Moreover, excellent temperature stability (70–130 °C) of the energy storage efficiency (less than 3%) was achieved.",

keywords = "Energy storage, Ferroelectrics, Lead-free, Perovskites, Sol-gel",

author = "S. Khardazi and H. Zaitouni and A. Neqali and S. Lyubchyk and D. Mezzane and M. Amjoud and E. Choukri and Z. Kutnjak",

note = "Publisher Copyright: {\textcopyright} 2023 Elsevier Ltd",

year = "2023",

month = jun,

doi = "10.1016/j.jpcs.2023.111302",

language = "English",

volume = "177",

journal = "Journal of Physics and Chemistry of Solids",

issn = "0022-3697",

publisher = "Elsevier Ltd.",

}

TY - JOUR

T1 - Enhanced thermal stability of dielectric and energy storage properties in 0.4BCZT-0.6BTSn lead-free ceramics elaborated by sol-gel method

AU - Khardazi, S.

AU - Zaitouni, H.

AU - Neqali, A.

AU - Lyubchyk, S.

AU - Mezzane, D.

AU - Amjoud, M.

AU - Choukri, E.

AU - Kutnjak, Z.

PY - 2023/6

Y1 - 2023/6

N2 - Polycrystalline lead-free Ba0.85Ca0.15Zr0.10Ti0.90O3 (BCZT), BaTi0.89Sn0.11O3 (BTSn) and 0.4Ba0.85Ca0.15Zr0.10Ti0.90O3–0.6BaTi0.89Sn0.11O3 (0.4BCZT–0.6BTSn) ferroelectric ceramics were prepared via sol-gel process and their structural, dielectric and energy storage properties were studied. Pure perovskite structure was confirmed by X-ray diffraction analysis. The evolution of energy storage performances with temperature was studied. A Significant recoverable energy-storage density of 137.86 mJ/cm3 and high energy-storage efficiency of 86.19% under a moderate electric field of 30 kV/cm were achieved in the composite 0.4BCZT–0.6BTSn ceramic at 353 K. Moreover, excellent temperature stability (70–130 °C) of the energy storage efficiency (less than 3%) was achieved.

AB - Polycrystalline lead-free Ba0.85Ca0.15Zr0.10Ti0.90O3 (BCZT), BaTi0.89Sn0.11O3 (BTSn) and 0.4Ba0.85Ca0.15Zr0.10Ti0.90O3–0.6BaTi0.89Sn0.11O3 (0.4BCZT–0.6BTSn) ferroelectric ceramics were prepared via sol-gel process and their structural, dielectric and energy storage properties were studied. Pure perovskite structure was confirmed by X-ray diffraction analysis. The evolution of energy storage performances with temperature was studied. A Significant recoverable energy-storage density of 137.86 mJ/cm3 and high energy-storage efficiency of 86.19% under a moderate electric field of 30 kV/cm were achieved in the composite 0.4BCZT–0.6BTSn ceramic at 353 K. Moreover, excellent temperature stability (70–130 °C) of the energy storage efficiency (less than 3%) was achieved.

KW - Energy storage

KW - Ferroelectrics

KW - Lead-free

KW - Perovskites

KW - Sol-gel

UR - http://www.scopus.com/inward/record.url?scp=85149418401&partnerID=8YFLogxK

U2 - 10.1016/j.jpcs.2023.111302

DO - 10.1016/j.jpcs.2023.111302

M3 - Article

AN - SCOPUS:85149418401

SN - 0022-3697

VL - 177

JO - Journal of Physics and Chemistry of Solids

JF - Journal of Physics and Chemistry of Solids

M1 - 111302

ER -

Enhanced thermal stability of dielectric and energy storage properties in 0.4BCZT-0.6BTSn lead-free ceramics elaborated by sol-gel method

Abstract

Bibliographical note

Funding

Keywords

Access to Document

Other files and links

Fingerprint

Cite this